Development of PFAS Alternatives in the Chemical Industry

PFAS: detecting, removing, replacing


The group of per- and polyfluoroalkyl substances (PFAS) comprises several thousand industrial chemicals used in a wide variety of industrial processes and products. However, in addition to their diverse and sometimes unique technical benefits, PFAS have undisputed harmful effects on nature, the environment and health. For this reason, the European Chemicals Agency (ECHA) has proposed to extensive restrictions on the production, use and supply (including import) of PFAS in 2023. As a result, the search for PFAS-free alternative materials has gained significant momentum in numerous industrial sectors.

 

The institutes of the Fraunhofer Chemistry Alliance conduct research and development on a wide range of PFAS-related topics, providing a uniquely broad range of expertise

 

This includes the detection analysis of PFAS substances and their metabolites, their environmental and human toxicological assessment, and regulatory issues. The development of the necessary methods is an important part of our work.

We are also working on concepts, methods and processes for the removal of PFAS from water and the environment, and for the targeted, safe degradation and disposal of PFAS materials.

The need for alternative materials to PFAS in a variety of technical applications and everyday products is currently of great urgency. We support companies in their search for tailor-made substitutes, in the modification and development of suitable materials, and in their testing and evaluation. This also includes issues relating to the adaptation of corresponding manufacturing and processing procedures if PFAS materials are to be substituted by alternative materials.

Fluorine-free coatings for food packaging and upholstery fabrics

Per- and polyfluoroalkyl substances (PFAS) are used, for example, to protect pizza boxes from grease or to make outdoor clothing weatherproof. These chemicals have been found in groundwater and in the human body. Some of these chemicals are now considered to be hazardous to health or even carcinogenic.


The European Union is now planning to ban certain critical PFAS and is supporting the development of substitutes for PFAS in four major collaborative projects, such as the EU project ZeroF. As part of this project, the Fraunhofer Institute for Silicate Research ISC is working with industrial companies and research institutes on solutions for PFAS-free food packaging and textiles.
 

Project ZeroF

PFAS Dialogue Day 2023

PFAS Dialogue Day 2023
© Fraunhofer Chemistry Alliance

Intensive exchange at the Fraunhofer Chemistry Alliance event "PFAS Ban: Urgent Tasks for Applied Research" on October 12, 2023

 

More than 40 representatives from the manufacturing industry, politics, research and society came together for the day-long event to discuss current problems and challenges related to so-called "perpetual chemicals".

 

Review PFAS Dialogue Day

"PFAS: a Hindrance to Innovation or a Driver of Innovation"

MEDICA TECH FORUM PFAS keynote speech
© MedicalMountains GmbH

Keynote Speech and Panel Discussion at the MEDICA TECH FORUM in Düsseldorf

 

On November 14, Dr. Stefan Löbbecke gave a keynote speech on "What are PFAS, what is the restriction procedure all about? (Neutral) entry point for audience and panelists" and discussed current solutions for PFAS substitution.

 

Program overview

Projects and Developments from our Institutes

 

Textile Finishing based on the Biopolymer Chitosan

A project coordinated by Fraunhofer IGB has successfully demonstrated how textiles can be finished using chitosan in combination with bio-based hydrophobic molecules – as an environmentally friendly alternative to perfluorinated chemicals. This innovation could replace PFAS finishes with fewer requirements. The developed formulas have already been successfully adapted to various materials, including paper and cardboard.

 

Project "ZeroF"

The project "ZeroF" aims to replace PFAS with renewable raw materials and non-toxic compounds. The materials developed should be water, oil and grease repellent and reduce environmental impact by at least 25%. The Fraunhofer ISC is focusing on the development of an omniphobic coating for textiles. The ISC's ORMOCER® system will be used as an alternative to PFAS and optimized through chemical composition, additives and nano- and microstructuring.

 

Anion Exchange Membrane Water Electrolyzer (AEM-WE)

"Our membranes make it possible to manufacture AEM-WEs that in principle do not require precious metals and do not contain per- and polyfluoroalkyl substances (PFAS). We are thus paving the way for innovative system architectures that are both inexpensive and environmentally friendly," says Dr. Taybet Bilkay-Troni, head of the Polymers and Electronics department at Fraunhofer IAP, explaining the advantages of the novel polymer technology.

 

Project "AtWaPlas"

PFAS are detectable in many soils and water bodies and are difficult to remove using conventional filtration technologies. Researchers at the Fraunhofer Institute IGB are successfully using a plasma-based technology. In the joint project "AtWaPlas", contaminated water is treated with ionized gas to break down PFAS molecular chains and remove the toxic substance at low cost.

 

Project "ZeroPM"

PM substances threaten the safety of water resources, which means that drinking water often has to be treated at great expense to remove contamination from these substances. PFAS are the most prominent example. The broad European research project "Zero pollution of persistent, mobile substances", or ZeroPM for short, is dedicated to the goal of zero pollution of persistent, mobile substances (PM).

 

Project "PerfluorAd®"

Energy and resource efficient method for the removal of per- and polyfluorinated chemicals (PFAS) from extinguishing waters

 

Analysis of Contaminants

Among other things, Fraunhofer IVV is researching the further development of measurement methods for trace substances and the determination of substances in complex matrices such as food, paper/board, biological samples and environmental samples. Research focuses on substances of concern such as SVHCs and POPs, e.g. fluorinated organics (PFAS, PFC), mineral oil compounds MOSH/MOAH, phthalates/plasticizers and flame retardants.